Read Topics in Current Chemistry, Volume 214: Transition Metal and Rare Earth Compounds: Excited States, Transitions, Interactions II

Topics in Current Chemistry, Volume 214: Transition Metal and Rare Earth Compounds: Excited States, Transitions, Interactions II

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Description:There exists a large literature on the spectroscopic properties of copper(II) com- 9 pounds. This is due to the simplicity of the d electron configuration, the wide variety of stereochemistries that copper(II) compounds can adopt, and the f- xional geometric behavior that they sometimes exhibit [1]. The electronic and geometric properties of a molecule are inexorably linked and this is especially true with six-coordinate copper(II) compounds which are subject to a Jahn-T- ler effect.However, the spectral-structural correlations that are sometimes d- wn must often be viewed with caution as the information contained in a typical solution UV-Vis absorption spectrum of a copper(II) compound is limited. Meaningful spectral-structural correlations can be obtained in a related series of compounds where detailed spectroscopic data is available. In the fol- 4 lowing sections two such series are examined; the six-coordinate CuF and 6 2+ Cu(H O) ions doped as impurities in single crystal hosts.Using low tempera- 2 6 ture polarized optical spectroscopy and electron paramagnetic resonance, a very detailed picture can be drawn about the geometry of these ions in both their ground and excited electronic states. We then compare the spectrosco- cally determined structural data with that obtained from X-ray diffraction or EXAFS measurements."We have made it easy for you to find a PDF Ebooks without any digging. And by having access to our ebooks online or by storing it on your computer, you have convenient answers with Topics in Current Chemistry, Volume 214: Transition Metal and Rare Earth Compounds: Excited States, Transitions, Interactions II. To get started finding Topics in Current Chemistry, Volume 214: Transition Metal and Rare Earth Compounds: Excited States, Transitions, Interactions II, you are right to find our website which has a comprehensive collection of manuals listed.
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ISBN: 3540679766

Description: There exists a large literature on the spectroscopic properties of copper(II) com- 9 pounds. This is due to the simplicity of the d electron configuration, the wide variety of stereochemistries that copper(II) compounds can adopt, and the f- xional geometric behavior that they sometimes exhibit [1]. The electronic and geometric properties of a molecule are inexorably linked and this is especially true with six-coordinate copper(II) compounds which are subject to a Jahn-T- ler effect.However, the spectral-structural correlations that are sometimes d- wn must often be viewed with caution as the information contained in a typical solution UV-Vis absorption spectrum of a copper(II) compound is limited. Meaningful spectral-structural correlations can be obtained in a related series of compounds where detailed spectroscopic data is available. In the fol- 4 lowing sections two such series are examined; the six-coordinate CuF and 6 2+ Cu(H O) ions doped as impurities in single crystal hosts.Using low tempera- 2 6 ture polarized optical spectroscopy and electron paramagnetic resonance, a very detailed picture can be drawn about the geometry of these ions in both their ground and excited electronic states. We then compare the spectrosco- cally determined structural data with that obtained from X-ray diffraction or EXAFS measurements."We have made it easy for you to find a PDF Ebooks without any digging. And by having access to our ebooks online or by storing it on your computer, you have convenient answers with Topics in Current Chemistry, Volume 214: Transition Metal and Rare Earth Compounds: Excited States, Transitions, Interactions II. To get started finding Topics in Current Chemistry, Volume 214: Transition Metal and Rare Earth Compounds: Excited States, Transitions, Interactions II, you are right to find our website which has a comprehensive collection of manuals listed.
Our library is the biggest of these that have literally hundreds of thousands of different products represented.

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Topics in Current Chemistry, Volume 214: Transition Metal and Rare Earth Compounds: Excited States, Transitions, Interactions II

Topics in Current Chemistry, Volume 214: Transition Metal and Rare Earth Compounds: Excited States, Transitions, Interactions II

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